Trace element concentrations in the Mexico‐Belize ejecta layer: A link between the Chicxulub impact and the global Cretaceous‐Paleogene boundary     

Jane Wigforss‐Lange  Vivi Vajda  Adriana Ocampo 《Meteoritics & planetary science》2007,42(11):1871-1882

Abstract— Four exposures of Chicxulub impact ejecta along the Mexico‐Belize border have been sampled and analyzed for major and trace element abundances. The ejecta deposits consist of a lower spheroid bed, containing clay and dolomite spheroids, and an upper diamictite bed with boulders and clasts of limestone and dolomite. The matrix of both beds is composed of clay and micritic dolomite. The rare earth element (REE) compositions in the matrix of both units show strong similarities in concentrations and pattern. Furthermore, the Zr/TiO₂ scatter plot shows a linear correlation indicating one source. These results indicate that the basal spheroid bed has the same source and was generated during the same event as the overlying diamictite bed, which lends support to a single‐impact scenario for the Albion Formation ejecta deposits. The elevated concentrations of non‐meteoritic elements such as Sb, As, U, and Zn in the matrix of the lower spheroid bed are regarded to have been derived from the sedimentary target rocks at the Chicxulub impact site. The positive Eu and Ce anomalies in clay concretion and in the matrix of the lower part of the spheroid bed in Albion Island quarry is probably related to processes involved in the impact, such as high temperature and oxidizing conditions. Analogous trace element anomalies have been reported from the distal Cretaceous‐Paleogene (K/T) boundary clay layer at different sites. Thus, the trace element signals, reported herein, are regarded to support a genetic link between the Chicxulub impact, the ejecta deposits along the Mexico‐Belize border, and the global K/T boundary layer.  相似文献   

An observational study of heat fluxes and their relationships with net radiation     

Dario Camuffo  Adriana Bernardi 《Boundary-Layer Meteorology》1982,23(3):359-368

Experimental evidence indicates that the diurnal behaviour of the fluxes of heat into the ground and into the atmosphere versus the net flux of radiation can be modelled by closed curves, the hourly values folowing one another in either a clockwise or counter clockfashion. A general formulation to express the different heat fluxes as a function of net radiation is proposed. This relationship between the different heat fluxes and can be expressed as a sum of three terms: the first indicates a direct proportionality to , the second gives the deviation from linearity and depends on /t, and the third gives the value of the flux when = 0. The formulae are then expressed as a function of time and the ratios between the heat fluxes and are evaluated. A comparison with the approximations generally used shows that the latter may be considered as particular cases of the more general equations proposed here.  相似文献   

Sediment hosted lead–zinc deposits of the Neoproterozoic Bambuí Group and correlative sequences, São Francisco Craton, Brazil: A review and a possible metallogenic evolution model   总被引：3，自引：0，他引：3  

Aroldo Misi  Sundaram S.S. Iyer  Carlos Eduardo S. Coelho  Colombo C.G. Tassinari  Washington J.S. Franca-Rocha  Ion de Abreu Cunha  Adriana S. Rocha Gomes  Tolentino Flvio de Oliveira  Joo Batista G. Teixeira  Valter Mnaco C. Filho 《Ore Geology Reviews》2005,26(3-4):263-304

The Proterozoic sediment-hosted Zn–(Pb) sulfide and non-sulfide deposits of the São Francisco Craton, Brazil, are partially syn-diagenetic and epigenetic and were probably formed during extensional events. The majority of the deposits occur within shallow water dolomites. The Pb isotopic data of sulfides are relatively homogeneous for individual deposits and plot above the upper crust evolution curve of the Plumbotectonic model. Some of the deposits are characterized by highly radiogenic lead (²⁰⁶Pb/²⁰⁴Pb ≥ 21) originating from the highly radioactive crust of the São Francisco Craton. Pb and S isotopic data suggest the sources of metal and sulfur for the deposits to be the basement rocks and seawater sulfates in the sediments, respectively. The relatively high temperatures of formation (100 to 250 °C) and moderate salinity (3% to 20% NaCl equiv.) of the primary fluid inclusions in the sphalerite crystals suggest the participation of basinal mineralizing fluids in ore formation. The steep paleo-geothermal gradient generated by the radioactively enriched basement rocks probably assisted in heating up the circulating mineralizing fluids.  相似文献   

The Gleissberg Cycle of Minima     

Garcia  Adriana  Mouradian  Zadig 《Solar physics》1998,180(1-2):495-498

In this short article we show that the sunspot cycle minima exhibit a long cycle (Gleissberg) in addition to the 11-yr cycle. From 1750 onwards, three periods of the Gleissberg cycle can be detected.  相似文献   

Surficial geology of the Chicxulub impact crater,Yucatan, Mexico     

Kevin O. Pope  Adriana C. Ocampo  Charles E. Duller 《Earth, Moon, and Planets》1993,63(2):93-104

The Chicxulub impact crater in northwestern Yucatan, Mexico is the primary candidate for the proposed impact that caused mass extinctions at the end of the Cretaceous Period. The crater is buried by up to a kilometer of Tertiary sediment and the most prominent surface expression is a ring of sink holes, known locally as cenotes, mapped with Landsat imagery. This 165 ± 5 km diameter Cenote Ring demarcates a boundary between unfractured limestones inside the ring, and fractured limestones outside. The boundary forms a barrier to lateral ground water migration, resulting in increased flows, dissolution, and collapse thus forming the cenotes. The subsurface geology indicates that the fracturing that created the Cenote Ring is related to slumping in the rim of the buried crater, differential thicknesses in the rocks overlying the crater, or solution collapse within porous impact deposits. The Cenote Ring provides the most accurate position of the Chicxulub crater's center, and the associated faults, fractures, and stratigraphy indicate that the crater may be 240 km in diameter.  相似文献   

Cathodoluminescence petrography and isotope geochemistry of KT impact ejecta deposited 360 km from the Chicxulub crater, at Albion Island, Belize     

Bruce W. Fouke  Aubrey L. Zerkle  Walter Alvarez†  Kevin O. Pope‡  Adriana C. OcampO§  Richard J. Wachtman  Jose Manuel Grajales Nishimura¶  Phillipe Claeys  & Alfred G. Fischer†† 《Sedimentology》2002,49(1):117-138

The depositional and diagenetic history of Cretaceous–Tertiary (KT) impact ejecta deposited 360 km from the Chicxulub crater, at Albion Island, Belize, has been investigated using integrated cathodoluminescence and isotopic analyses. A quarry exposes 26 m of Upper Cretaceous Barton Creek Formation dolomitized marine limestone overlain by 16 m of dolomitized Albion Formation impact ejecta. The Albion Formation consists of a lower fine‐grained ≈1‐m‐thick spheroid bed and an upper 15‐m‐thick coarse conglomeratic diamictite bed. A 14‐event paragenetic sequence has been documented and used as a temporal framework to interpret chemostratigraphic trends in bulk rock δ¹⁸O, δ¹³C and ⁸⁷Sr/⁸⁶Sr. The uppermost surface of the Barton Creek Formation was subaerially exposed before the KT impact, as indicated by a brecciated palaeosol that caps upsection decreases in δ¹³C and δ¹⁸O. Small 1‐cm‐diameter spheroids in the spheroid bed exhibit vermicular crystalline textures but lack the concentric zonations common to accretionary lapilli. These spheroids are hypothesized originally to have been impact glass or reactive Ca and Mg oxide dusts that adhered to water vapour particles condensing from the cooling impact vapour cloud. The spheroids were dolomitized soon after deposition. The earliest dolomitization in the matrix sediments of the Albion Formation was also post‐depositional, replacing clays formed by devitrification of impact glass. Dolomite and clay ⁸⁷Sr/⁸⁶Sr exhibit a distinct symmetrical distribution in the spheroid bed ranging from 0·707745 to 0·707872. Although unproven, this may represent primary changes in the chemical composition of the impact glass. The limestone clasts in the diamictite bed were dolomitized before the KT impact and exhibit upsection decreases in bulk rock ⁸⁷Sr/⁸⁶Sr. This suggests that the clasts were excavated from strata equivalent in age or older than the Barton Creek Formation at locations closer to, or in, the Chicxulub crater.  相似文献   

Textural properties vs. CEC and EGME retention of Na–X zeolite prepared from fly ash at room temperature     

Arkadiusz Derkowski  Wojciech Franus  Halina Waniak-Nowicka  Adriana Czímerová 《International Journal of Mineral Processing》2007

Zeolite Na–X (FAU type) was synthesized from F-class fly ash in simple and economical way. Several months of storage of fly ash in NaOH solution, at room temperature, without any prior treatment, results in the production of material with ca. 50% content of Na–X zeolite. The most efficient reaction takes place at (OH)⁻ activity of 0.1–0.15 mol (OH)⁻/g of ash and at S/L ratio of 33 to 67 g/dm³. Higher S/L value causes an accelerating dissolution–crystallization equilibrium attainment. Cl⁻ ion acts as the inhibitor of this reaction.  相似文献   

Diffuse Component Spectra of Solar Active Regions at Submillimeter Wavelengths     

Adriana?V.?R.?SilvaEmail author  Tatiana?F.?Laganá  C.?Guillermo?Gimenez?De?Castro  Pierre?Kaufmann  Joaquim?E.?R.?Costa  Hugo?Levato  Marta?Rovira 《Solar physics》2005,227(2):265-281

Solar maps at 212 and 405 GHz obtained by the Solar Submillimetric Telescope (SST) show regions of enhanced brightness temperature, which coincide with the location of active regions. A statistical study of the radio emission from these active regions was performed for the first time at such high frequencies during 23 days on June and July 2002, when the atmospheric opacity was low. The brightest regions on the maps were chosen for this study, where the brightness excess observed varies from 3 to 20% above quiet Sun levels (i.e., 200–1000 K) at both wavelengths. Sizes of the regions of enhanced emission calculated at half the maximum value were estimated to be between 2′ and 7′. These sizes agree with observed sizes of active regions at other wavelengths such as Hα and ultraviolet. An important result is that the flux density spectra of all sources increase toward submillimeter frequencies, yielding flux density spectral index with an average value of 2.0. The flux density of the active region sources were complemented with that from maps at 17 and 34 GHz from the Nobeyama Radio Heliograph. The resulting spectra at all four frequencies were fit considering the flux density to be due to thermal bremsstrahlung from the active region. In the calculations, the source radius was assumed to be the mean of the measured values at 212 and 405 K. The effective temperatures of the radio emitting source, assumed homogeneous, obtained from this fit were 0.6–2.9 × 10⁴ K, for source diameters of 2′–7′.  相似文献   

Late Holocene marine terraces of the Cartagena region,southern Caribbean: The product of neotectonism or a former high stand in sea-level?     

J. Ignacio Martínez  Yusuke Yokoyama  Andres Gomez  Adriana Delgado  Hiroyuki Matsuzaki  Esteban Rendon 《Journal of South American Earth Sciences》2010,29(2):214-224

The detailed stratigraphic survey and paleontological study (mollusks, corals, foraminifera and ostracods) of four low-level, ～3 m, marine terrace sections: Punta Canoas, Manzanillo del Mar, Playa de Oro, and Tierra Bomba Island, from the Cartagena region, southern Caribbean, supplemented with 22 radiocarbon dates, reveals that the northern terraces were deposited as parasequences in a clastic depositional system compared to the Tierra Bomba Island succession that was deposited in a carbonate depositional system between ～3600 and ～1700 cal yrs BP. Drier conditions and the southern location of the ITCZ at about 3 ka triggered stronger easterly Trades and more dynamic southwestward sediment drift fed by the Magdalena River mouth, thus promoting the formation of sand spits that ultimately isolated the Cienaga de Tesca coastal lagoon from the Caribbean Sea. Our estimates support the hypothesis that the present position of the terraces is the product of neotectonism rather than a higher 3 ka, sea-level. Upheaval of the terraces varies between ～3.8 mmyr^?1 at Punta Canoas and ～2.2 mmyr^?1 at Tierra Bomba to ～1.5 mmyr^?1 at Manzanillo del Mar and Playa de Oro terraces. Our study corroborates previous contentions on the role of mud diapirism and the dynamics of the Dique Fault as late Holocene upheaval mechanisms.  相似文献   

Phylogeographic patterns in Maguimithrax spinosissimus (Decapoda: Mithracidae) from Colombian Caribbean     

Julio César Hurtado-Alarcón  Néstor Hernando Campos Campos  Adriana Bermúdez Tobón  Edna J. Márquez 《新西兰海洋与淡水研究杂志》2018,52(1):118-137

The Caribbean king crab Maguimithrax spinosissimus is an important artisanal fisheries resource with a distribution range that includes the Florida Keys and Caribbean Sea islands. We carried out a phylogeographic analysis of M. spinosissimus in one oceanic (Old Providence) and two continental islands (Rosario and Tintipán). We analysed 89 and 49 Control Region (CR) and Cytochrome Oxidase I (COI) sequences, respectively. We found genetic differentiation between Old Providence and Rosario?+?Tintipán units (F_ST values of 0.84 for CR and 0.91 for COI gene), and gene flow between Rosario and Tintipán (F_ST values ?0.0085 for CR, P?>?.88; ?0.01 for COI gene, P?>?.99). Our analysis showed two genetic stocks and possibly an isolated biogeographic unit of M. spinosissimus. We suggest managing the species as different populations, and conducting more ecological and biological studies for the determination of possible cryptic species.  相似文献